Citation: Yan SHI, Zhi Feng FU, Yu Dong ZHANG, Shu Ke JIAO. Synthesis of Comblike Poly(methyl methacrylate) by Atom Transfer Radical Polymerization with Poly(ethyl 2-bromoacrylate) as Macroinitiator[J]. Chinese Chemical Letters, ;2003, 14(12): 1289-1292. shu

Synthesis of Comblike Poly(methyl methacrylate) by Atom Transfer Radical Polymerization with Poly(ethyl 2-bromoacrylate) as Macroinitiator

1.
Key Laboratory of Controlled Chemical Reactions, and Department of Polymer Engineering, Beijing University of Chemical Technology, Beijing 100029;
2.
Polyolefin National Engineering Research Center, Beijing Research Institute of Chemical Industry, Beijing 100013

Received Date: 3 December 2002

Comblike poly(methyl methacrylate) was synthesized by atom transfer radical polymerization of methyl methacrylate with poly(ethyl 2-bromoacrylate) as a macroinitiator, which was prepared by conventional free radical polymerization of ethyl 2-bromoacrylate. The obtained comblike polymers were characterized by GPC and ¹H NMR.
- Comblike polymer,
- atom transfer radical polymerization (ATRP),
- macroinitiator,
- poly(methyl methacrylate),
- ethyl 2-bromoacrylate
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