Citation: Bao Hui YE, Tian Xian ZENG, Liang Nian JI, Hong Hui ZHUANG. THE SYNTHESIS AND CRYSTAL STRUCTURE OF CIS-BIS(1, 10-PHENANTHROLINE)GLYCINECOBALT(Ⅲ)[J]. Chinese Chemical Letters, ;1991, 2(7): 529-530. shu

THE SYNTHESIS AND CRYSTAL STRUCTURE OF CIS-BIS(1, 10-PHENANTHROLINE)GLYCINECOBALT(Ⅲ)

a Chemistry Department of Zhongshan University Guangzhou 510275;
b Fuzhou Research Laboratory of Structural Chemistry Chinese Academy of Sciences

Received Date: 3 May 1991

A new coordination compound of cis-bis(1, 10-phenanthroline)glycinecobalt(Ⅲ)chloridate tetrahydrate, cis-[Co(phen)₂gly]Cl₂.4H₂O, has been prepared by glycine reacted with cis-[Co(phen)₂Cl₂]Cl, then isolated by SP-Sephadex C-25 H⁺ form column.The crystal and molecular structure of the new compound has been determined by RIGAKUAFC5R four circle diffractometer, 5032 independent reflections were collected of which 3781 observable reflections were used for structure refinement.The crystal is monoclinic, space group C2/c, with a=35.13(1) Å, b=9.637(3) Å, c=17.485(6) Å, β=115.08(2)^a, V=5362(3) Å³, Z=8.The structure was refined by full matrix least-squares procedure to a final R=0.041 and R_ω=0.060.The molecular formula was CoC₂₈H₂₈N₅O₈Cl₂.with molecular weight M_r=636.38, D_c=1.58g/cm³, μ=8.88cm^-1 and F₍₀₀₀₎=2624.
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