Citation: HE Pingsheng, PELTONEN J.P.K., ROSENHOLM J.B. ELASTICITY OF MONOLAYER OF LINOLEIC ACID AND ITS POLYMER*[J]. Chinese Journal of Polymer Science, ;1998, 16(2): 147-154. shu

ELASTICITY OF MONOLAYER OF LINOLEIC ACID AND ITS POLYMER*

Received Date: 25 March 1997

The dynamic elasticity of linoleic acid monolayer on a subphase of10-4mol/L TbCl3 at various surface pressure has been measured by means of dynamic oscil-lation method in measuring the change of surface pressure caused by periodic compression-expansion cycles of the barrier. The elasticity of monolayer increases with increasing ofsurface pressure linearly. The linoleic acid polymer monolayer has been obtained underUV-irradiation in situ when keeping a constant surface pressure. But the elasticity of the resulting polymerized monolayer is even smaller than that of its corresponding monomer monolayer.The elasticity of the polymerized linoleic acid monolayer decreases with increasing polymerization time.The explanation based on entropy has been presented.
1. [1]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
2. [2]
  Fangzhou Li , Liang Gao , Linping Wang , Ben-Lin Hu . Unlocking the elasticity in ferroelectrics by slight crosslinking. Chinese Journal of Structural Chemistry, 2025, 44(3): 100443-100443. doi: 10.1016/j.cjsc.2024.100443
3. [3]
  Chuansong LIN , Chuqing ZHANG , Shixiong LI . A Ni(Ⅱ) metal-organic framework based on the 4, 4′-biphenyldicarboxylic acid ligand and its adsorption performance for tetracycline. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 593-605. doi: 10.11862/CJIC.20250278
4. [4]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
5. [5]
  Lizhi Wang , Chuanxin Wei , Xinyu Du , Yingying Zheng , Shuang Li , Ning Sun , Zhiqiang Zhuo , Ningning Yu , Yingru Lin , Zhiyang Sun , Jinyi Lin , Man Xu , Yongzheng Chang , Tianshi Qin , Zhoulu Wang , Xuehua Ding , Wei Huang . Energy engineering and mechanical elasticity of molecular crystals via supramolecular salt strategy for flexible visible optical waveguide. Chinese Chemical Letters, 2026, 37(2): 111634-. doi: 10.1016/j.cclet.2025.111634
6. [6]
  Yujuan Zhao , Zaiwang Zhao . Monolayer mesoporous nanosheets with surface asymmetry via a dual-emulsion-directed monomicelle assembly. Chinese Journal of Structural Chemistry, 2024, 43(2): 100238-100238. doi: 10.1016/j.cjsc.2024.100238
7. [7]
  Jiayi Lu , Yizhang Li , Hao Jiang , Zhiwen Zhu , Fengru Zheng , Qiang Sun . Preparing sub-monolayer metals with continuous coverage spread for high-throughput growth of metal-organic frameworks. Chinese Chemical Letters, 2025, 36(3): 110394-. doi: 10.1016/j.cclet.2024.110394
8. [8]
  Xiaoli Deng , Xiangchao Lu , Yang Cao , Qianjin Chen . Electrochemical imaging uncovers the heterogeneity of HER activity by sulfur vacancies in molybdenum disulfide monolayer. Chinese Chemical Letters, 2025, 36(3): 110379-. doi: 10.1016/j.cclet.2024.110379
9. [9]
  Jiajun Wang , Chen Sun , Li Sheng , Zhiwen Zhuo , Shujuan Li , Jiayao Wang , Weiyi Wang , Jinbo Sun , Juqian Yang , Ke Xu , Shulai Lei . Unveiling the electrocatalytic potential of main-group metal-embedded BC₃ monolayer for highly efficient NO reduction to NH₃. Chinese Chemical Letters, 2026, 37(5): 110974-. doi: 10.1016/j.cclet.2025.110974
10. [10]
  Hongen Cao , Xinrui Xiao , Xu Zhang , Yiyang Zhang , Lei Yu . Element Transfer Reaction theory: Scientific connotation and its applications in chemical industry. Chinese Chemical Letters, 2025, 36(9): 110924-. doi: 10.1016/j.cclet.2025.110924
11. [11]
  Mengdie Li , Shundong Cai , Hongjin Li , Yuhang Cheng , Jinfa Ye , Lang Ke , Yun Han , Min Su , Gang Liu , Chengchao Chu . Nanotherapeutics for ocular posterior segment diseases therapy: Towards its advances and challenges. Chinese Chemical Letters, 2026, 37(5): 111392-. doi: 10.1016/j.cclet.2025.111392
12. [12]
  Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
13. [13]
  Yaohua Li , Qi Cao , Xuanhua Li . Tailoring the configuration of polymer passivators in perovskite solar cells. Chinese Journal of Structural Chemistry, 2025, 44(2): 100413-100413. doi: 10.1016/j.cjsc.2024.100413
14. [14]
  Dayang Xie , Qiannan Cao , Huapan Fang , Yanhui Li , Huayu Tian . Applications and challenges of biomedical polymer materials in pulmonary diseases. Chinese Chemical Letters, 2026, 37(2): 111032-. doi: 10.1016/j.cclet.2025.111032
15. [15]
  Qingxuan Kong , Changwei Jiang , Bin Lyu , Zhaoting Li , Ning Jiao , Song Song . Denitrative iodination of nitroarenes with hydroiodic acid. Chinese Chemical Letters, 2025, 36(10): 111444-. doi: 10.1016/j.cclet.2025.111444
16. [16]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
17. [17]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
18. [18]
  Huimin Gao , Zhuochen Yu , Xuze Zhang , Xiangkun Yu , Jiyuan Xing , Youliang Zhu , Hu-Jun Qian , Zhong-Yuan Lu . A mini review of the recent progress in coarse-grained simulation of polymer systems. Chinese Journal of Structural Chemistry, 2024, 43(5): 100266-100266. doi: 10.1016/j.cjsc.2024.100266
19. [19]
  Dong Lv , Xuelei Liu , Wei Li , Qiang Zhang , Xinhong Yu , Yanchun Han . Single droplet formation by controlling the viscoelasticity of polymer solutions during inkjet printing. Chinese Chemical Letters, 2024, 35(6): 109401-. doi: 10.1016/j.cclet.2023.109401
20. [20]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1478)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return