Citation: Yun Yan GAO, Chang Jiang YOU, Jin Ping CHEN, Yong Yong LIU, Bao Wen ZHANG, Yi LI. Synthesis of a Polymer-bound Sensitizer and its Application in the Photoisomerization of trans-Vitamin D₃ to cis-Vitamin D₃[J]. Chinese Chemical Letters, ;2002, 13(12): 1158-1161. shu

Synthesis of a Polymer-bound Sensitizer and its Application in the Photoisomerization of trans-Vitamin D₃ to cis-Vitamin D₃

Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101

Received Date: 1 March 2002

Fund Project: This work was supported by the Ministry of Science and Technology of China (Grant No.G2000078100), the National Natural Science Foundation of China (No.20172059) and Chinese Academy of Sciences.

A polymer-bound photosensitizer was synthesized by the reaction of Merrifield resin with 9-anthracenemethanol in the presence of potassium hydride. The photoisomerization of trans-vitamin D₃ to cis-vitamin D₃ was carried out with this polymer-bound photosensitizer in ethanol and toluene solutions. The experiment results demonstrate that this solid photosensitizer is efficient for the photoismerization and easy for separation from the reaction mixtures.
- Photoisomerization,
- solid phase sensitizer,
- vitamin D₃
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3. [3]
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4. [4]
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5. [5]
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7. [7]
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8. [8]
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9. [9]
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15. [15]
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16. [16]
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18. [18]
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19. [19]
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20. [20]
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