Citation: . SYNTHESIS AND PROPERTIES OF NEW SIDE-CHAIN LIQUID CRYSTALLINE POLYMER WITH LATERALLY ATTACHED MESOGENS BY ESTER GROUP*[J]. Chinese Journal of Polymer Science, ;1999, 17(5): 499-509.
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New liquid crystalline monomer, 2,5-bis[(4'-methoxyphenoxy)carbonyl]phenyl acrylate wassuccessfully synthesized. Polyacrylate with laterally attached mesogens via ester linkage was also derived.This polymer forms an enantiotropic liquid crystal phase while its monomer exhibits a metastable nematicphase with respect to the crystalline state. However, its liquid crystallinity is very low as compared to that ofpoly{2,5-bis[(4'-methoxyphenoxy)carbonyl]-styrene}.
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