Citation: Li Xiaolong, Li Buyun, Yang Tao, Li Wanfu, Hua Shaochun. Synthesis of Novel "114" Configuration Oxides and Its Structure Evolution Induced by ion Doping[J]. Chemistry, ;2018, 81(5): 439-444. shu

Synthesis of Novel "114" Configuration Oxides and Its Structure Evolution Induced by ion Doping

Li Xiaolong ^1,2, ,
Li Buyun ¹ ,
Yang Tao ¹ ,
Li Wanfu ² ,
Hua Shaochun ²

1.
Southwest Technology and Engineering Research Institute, Chongqing 400039
2.
PLA Rocket Force of the representative office in Chongqing, Chongqing 400039

Received Date: 21 November 2017
Accepted Date: 8 March 2018

Figures(11)

With special tetrahedral layer in the structure, "114" compounds have potential application value in terms of magnetics and oxygen storage. In this article, conventional high-temperature solid-state reaction method is used to synthesize new compound YBaZn₃GaO₇, in which Sc³⁺ with smaller effective radius is doped in octahedral site to obtain the total solid solution compound Y_1-xSc_xBaZn₃GaO₇(x=0~1). Structural refining determines the space group of the series of "114" compounds to be P6₃mc, and structural analysis shows that the structure has obvious evolution trend with increasing doping amount. From YBaZn₃GaO₇ to ScBaZn₃GaO, the cell parameter decreases linearly. In addition, according to analysis on bond length of each coordination element, increasing doping quantity may reduce structural aberration and stress to allow for integration of Zn²⁺ and Ga³⁺ in tetrahedral coordination, thus obtaining "114" compounds with more stable structure.
- High temperature solid phase method,
- Doping,
- Structure evolution
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