Citation: Long YU, Shu Qing LI, Wen Qin FANG. SYNTHESIS AND CHARACTERIZATION OF FOUR NOVEL TYPES OF MICROPOROUS BERYLLOPHOSPHATE(Ⅱ)[J]. Chinese Chemical Letters, ;1992, 3(6): 473-476. shu

SYNTHESIS AND CHARACTERIZATION OF FOUR NOVEL TYPES OF MICROPOROUS BERYLLOPHOSPHATE(Ⅱ)

a Department of Chemistry Liaoning University Shenyang 110036;
b Department of Chemistry Jilin University Changchun 130023

Received Date: 8 January 1992

Four new types of microporous beryllophosphates werehydrothermally synthesized using BeO- P₂O₅- R- MCl (or MCl₂)- H₂0, Rbeing HMDA (1, b-hexanediamine), EDA (ethylenediamine), or TBAOH(tetrabutytamine hydroxide), M alkali or alkali earth cation.By means ofX-ray diffraction patterns (XRD), infrared (IR), TG-DT and elemental analyseswe show that the crystalline beryllopbospbates have novel, unique frameworkstructures, composed from basic units of tetrahedral P0₄ and Be0₄.Thesematerials exhibit zeolite-like adsorption and ion-exchange properties
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