Citation: Wang Xuan, Li Kuo, Zheng Haiyan, Zhang Peijie. Chemical Reactions of Molecules under High Pressure[J]. Chemistry, ;2019, 82(5): 387-398. shu

Chemical Reactions of Molecules under High Pressure

Center for High Pressure Science and Technology Advanced Research, Beijing 100094

Corresponding author: Li Kuo, likuo@hpstar.ac.cn
Received Date: 3 December 2018
Accepted Date: 6 February 2019

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Under high pressure (1~100 GPa and above), the composition, structure and chemical reaction of matters change significantly, and it is of great significance to understand the chemical reactions under high pressure. In general, molecules solidify under external pressure, unsaturated molecules tend to polymerize to form covalently bonded saturated material with higher density; diffusions of molecules and atoms are significantly restricted, and metastable compounds are often generated; the crystal structure of the reactants, the properties of the functional groups, the temperature and hydrostaticity have significant effects on the reaction. In situ and ex situ crystallography, spectroscopy, chemical characterization, and theoretical calculations are important for the study of the reaction process, and every effort on the synthesis, characterization, theoretical calculation under high pressure is a new step towards the interesting world under extreme condition.
- High pressure chemistry,
- Molecular crystal,
- Ionic compound,
- Extreme condition,
- in situ characterization
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