Citation: JIANG Donglin, ZHANG Yifeng, SHEN Zhiquan. EFFECT OF CHEMICAL STRUCTURE OF SULFOXIDE GRAFTED POLY (VINYL ALCOHOL) ON GAS PERMEABILITY*[J]. Chinese Journal of Polymer Science, ;1994, 12(2): 132-136. shu

EFFECT OF CHEMICAL STRUCTURE OF SULFOXIDE GRAFTED POLY (VINYL ALCOHOL) ON GAS PERMEABILITY*

Received Date: 23 November 1992

The effects of chemical structure, i. e. side chain structure and their contents, on thepermeability of pure SO2, N2 and their mixture gases for the sulfoxide grafted poly (vinylalcohol) (RVSO-PVA) membranes have been investigated:where R=Me, Et, Pr, t-Bu and Ph. It was notable that introduction of sulfoxide group intoPVA side chain greatly enhanced the permselectivity of sulfur dioxide. SO2 permeability andseparation factor of these polymers increased markedly as the size of side chain increased. The sulfoxide content of the polymer also played an important role in the pure and mixture gases permeation.Some explanations have been made to interpret this unique gas separation behaviour.
1. [1]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
2. [2]
  Min Fu , Pan He , Sen Zhou , Wenqiang Liu , Bo Ma , Shiying Shang , Yaohao Li , Ruihan Wang , Zhongping Tan . An unexpected stereochemical effect of thio-substituted Asp in native chemical ligation. Chinese Chemical Letters, 2024, 35(8): 109434-. doi: 10.1016/j.cclet.2023.109434
3. [3]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
4. [4]
  Chenlu Huang , Xinyu Yang , Qingyu Yu , Linhua Zhang , Dunwan Zhu . Gas-generating polymersomes-based amplified photoimmunotherapy for abscopal effect and tumor metastasis inhibition. Chinese Chemical Letters, 2024, 35(6): 109680-. doi: 10.1016/j.cclet.2024.109680
5. [5]
  Tong Tong , Lezong Chen , Siying Wu , Zhong Cao , Yuanbin Song , Jun Wu . Establishment of a leucine-based poly(ester amide)s library with self-anticancer effect as nano-drug carrier for colorectal cancer treatment. Chinese Chemical Letters, 2024, 35(12): 109689-. doi: 10.1016/j.cclet.2024.109689
6. [6]
  Min Huang , Ru Cheng , Shuai Wen , Liangtong Li , Jie Gao , Xiaohui Zhao , Chunmei Li , Hongyan Zou , Jian Wang . Ultrasensitive detection of microRNA-21 in human serum based on the confinement effect enhanced chemical etching of gold nanorods. Chinese Chemical Letters, 2024, 35(9): 109379-. doi: 10.1016/j.cclet.2023.109379
7. [7]
  Jingyu Shi , Xiaofeng Wu , Yutong Chen , Yi Zhang , Xiangyan Hou , Ruike Lv , Junwei Liu , Mengpei Jiang , Keke Huang , Shouhua Feng . Structure factors dictate the ionic conductivity and chemical stability for cubic garnet-based solid-state electrolyte. Chinese Chemical Letters, 2025, 36(5): 109938-. doi: 10.1016/j.cclet.2024.109938
8. [8]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416
9. [9]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
10. [10]
  Xinzhe ZHANG , Jiarong XU , Mochou GAO , Yage LIU , Yanbao ZHAO , Jingzeng CUI , Xueyan ZOU . Silver chloride/chitosan-based chloramine nanohybrid with excellent antibacterial activity: Design and structure characterization as well as Ag⁺-Cl^- synergistic antibacterial effect. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 428-438. doi: 10.11862/CJIC.20250123
11. [11]
  Zhen Liu , Xinyi Xu , Jinkai He , Fei Xu , Qian Li . Revealing the synergistic effect of materials composition and pollutants structure on catalytic degradation mechanism in heterogeneous iron-based Fenton-like reactions. Chinese Chemical Letters, 2026, 37(4): 111644-. doi: 10.1016/j.cclet.2025.111644
12. [12]
  Da-Qiu Cui , Quan-Xin Li , Jia-Bo Huang , Ying-Qi Zhang , Xuan Wang , Shao-Fei Ni , Long-Wu Ye , Bo Zhou . Atroposelective transformation of vinyl cations by chiral Brønsted acid catalysis. Chinese Chemical Letters, 2026, 37(6): 111738-. doi: 10.1016/j.cclet.2025.111738
13. [13]
  Haojie Song , Laiyu Luo , Siyu Wang , Guo Zhang , Baojiang Jiang . Advances in poly(heptazine imide)/poly(triazine imide) photocatalyst. Chinese Chemical Letters, 2024, 35(10): 109347-. doi: 10.1016/j.cclet.2023.109347
14. [14]
  Cong-Bin Ji , Ding-Xiong Xie , Mei Chen , Ye-Ying Lan , Bao-Hua Zhang , Ji-Ying Yang , Zheng-Hui Kang , Shu-Jie Chen , Yu-Wei Zhang , Yun-Lin Liu . Green synthesis of 2-trifluoromethylquinoline skeletons via organocatalytic N-[(α-trifluoromethyl)vinyl]isatins CN bond activation. Chinese Chemical Letters, 2025, 36(7): 110598-. doi: 10.1016/j.cclet.2024.110598
15. [15]
  Tianzhu Qin , Weiwei Zi . Palladium-catalyzed enantioselective [2σ + 2π] cycloadditions of vinyl-carbonyl-bicyclo[1.1.0]butanes with arylidenemalononitriles. Chinese Chemical Letters, 2026, 37(1): 111072-. doi: 10.1016/j.cclet.2025.111072
16. [16]
  Qian Wang , Ting Gao , Xiwen Lu , Hangchao Wang , Minggui Xu , Longtao Ren , Zheng Chang , Wen Liu . Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor. Chinese Chemical Letters, 2024, 35(7): 108887-. doi: 10.1016/j.cclet.2023.108887
17. [17]
  Lingyao Zhang , Chunhui Zhang , Yingjia Sun , Qinglin Yang , Ziwei Guo , Xiaoqi Wang , Kang Wang , Lin Zhang , Kesong Liu , Shichao Niu , Cunming Yu , Lei Jiang . Bioinspired underwater gas diffusion enhanced by superaerophilic stripe. Chinese Chemical Letters, 2026, 37(5): 111720-. doi: 10.1016/j.cclet.2025.111720
18. [18]
  Manman Ou , Yunjian Zhu , Jiahao Liu , Zhaoxuan Liu , Jianjun Wang , Jun Sun , Chuanxiang Qin , Lixing Dai . Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots. Chinese Chemical Letters, 2025, 36(2): 110510-. doi: 10.1016/j.cclet.2024.110510
19. [19]
  Jingxiong Jiang , Yao Dong , Yuchun Wang , Lijuan Qi , Zhen-Yu Li , Tai-Bao Wei , Wen-Juan Qu , Qi Lin , Bingbing Shi . Separation of toluene-alcohol azeotropes by porous crystals of fluorinated leaning pillar[6]arene. Chinese Chemical Letters, 2025, 36(8): 110759-. doi: 10.1016/j.cclet.2024.110759
20. [20]
  Yufeng ZHANG , Haotian QI , Jingya ZHONG , Leiming LANG , Guojun YUAN , Siqi LU , Haiying WANG , Guangxiang LIU . S-anion effects on the improvement of adsorption capacity and performance for benzyl alcohol electro-oxidation catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2591-2600. doi: 10.11862/CJIC.20250282

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1566)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return