Citation: Yun Feng YAO, Mai Sheng ZHANG, Yan Sheng YANG, Qiang SU, Hong Jie ZHANG. A Transparent Thin Film with Hexagonal Mesostructure Containing Rhodamine 6G[J]. Chinese Chemical Letters, ;2002, 13(5): 464-467.
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A transparent thin film was prepared by depositing the sol-gel mixture for the synthesis of MCM-41 mesoporous molecular sieve doped with rhodamine 6G (R6G) dye on glass substrates. The film of silica-surfactant-R6G materials, which was identified to possess hexagonally ordered mesostructure, was composed of nanocrystallites about 35 nm in diameter and 1-10(m in thickness. Cleanness of the substrates, concentration of the sol-gel mixture and rate of evaporation of the solvent were the key factors affecting transparency and homogeneity of the film. Moreover, optical change and lack in dye aggregation were observed to the R6G-functionalized MCM-41 thin film in contrast with that in ethanol solution.
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