Citation: De Jie ZHAO, Jin Kun HUANG, Zi Xing SHAN. A NEW ROUTE FROM HETEROAROMATIC BORON COMPOUNDS TO CORRESPONDING KETONES VIA DICHLOROCARBENE INSERTION UNDER PHASE TRANSFER CONDITIONS[J]. Chinese Chemical Letters, ;1993, 4(5): 385-386. shu

A NEW ROUTE FROM HETEROAROMATIC BORON COMPOUNDS TO CORRESPONDING KETONES VIA DICHLOROCARBENE INSERTION UNDER PHASE TRANSFER CONDITIONS

Department of Chemistry, Wuhan University, Wuhan, 430072

Received Date: 7 November 1992

Fund Project: This work was supported by the National Natural Science Foundation of China.

The reactions of tri-2-benzofuranylborane or aminoethyl di-2-thienylborinate and 2-thienylphenylborinate with dichlorocarbene generated in situ from chloroform under phase transfer conditions were explored as a new route for the preparation of heteroaromatic ketones. It was found that a good yield of the ketones can be obtained by solid-liquid system.
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