Citation: Hua JIANG, Hui Jun XU, Pei Jie XIA, Qing Fu ZHOU. Synthesis and Effect of Cation Binding on Photophysical Properties of 1,8-Anthraceno-18-Crown-5[J]. Chinese Chemical Letters, ;1999, 10(12): 1015-1018. shu

Synthesis and Effect of Cation Binding on Photophysical Properties of 1,8-Anthraceno-18-Crown-5

Laboratory of Photochemistry Institute of Photographic Chemistry Chinese Academy of Sciences Beijing 100101

Received Date: 19 July 1999

Fund Project: This work was supported by the National Natural Science Foundation of China (Project No:29733100)

A new type of anthracene crown ether 1,8-anthraceno-l8-crown-5 has been synthesized and the photophysical properties upon complexation with alkali and alkaline-earth metal cations were investigated.The fluorescence quantum yield and lifetime are appreciably enhanced, and the stability constant Ks were determined by fluorometric titration. It was found that the magnitude of Ks is controlled by the size and charge density of the complexed cations.
- Crown ether,
- photophysical property,
- canon-binding
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