Citation: Chun Hui ZHOU, Hong Qiang GUO, Hui Jun CAO, Xiao Nian LI, Zhong Hua GE, Jie LI. Synthesis and Characterization of Novel Layered Lithium Sodium Silicate (Silinaite) and the Mesoporous Materials from Silinaite[J]. Chinese Chemical Letters, ;2006, 17(4): 525-528. shu

Synthesis and Characterization of Novel Layered Lithium Sodium Silicate (Silinaite) and the Mesoporous Materials from Silinaite

College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032

Received Date: 11 July 2005

Fund Project: Fund supports by the National Natural Science Foundation of China (No.20541002) and Zhejiang Provincial Natural Science Foundation (No.Y405064) are acknowledged.

Novel layered silinaite has been synthesized using an aqueous mixture of water glass, LiOH and NaOH under hydrothermal crystallization. Subsequently transformation of silinaite into mesoporous materials (SDM) was achieved at mild condition using cetyltrimethylammonium bromide as structure-directing agents. The resulting samples were characterized by XRD, SEM, FTIR nitrogen adsorption-desorption isotherms and catalytic performance in bulky molecular involved reaction. The results revealed that synthesized mesoporous materials derived from the silinaite exhibited an ordered hexagonal crystal structure with average pore diameter 2.7 nm and BET surface area 817m²/g. The SDM-supported ZnCl₂ catalyst, prepared by impregnationevaporation method, retained the mesoporous structure and showed high selectivity in alkylation of benzene with benzyl chloride.
- Silinaite,
- mesoporous materials,
- layered solid,
- catalysts,
- characterization
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