Citation: . SYNTHESIS OF POLY(VINYL ACETATE)-INTERCALATED GRAPHITE OXIDE BY AN IN SITU INTERCALATIVE POLYMERIZATION*[J]. Chinese Journal of Polymer Science, ;2000, 18(5): 413-418. shu

SYNTHESIS OF POLY(VINYL ACETATE)-INTERCALATED GRAPHITE OXIDE BY AN IN SITU INTERCALATIVE POLYMERIZATION*

Received Date: 15 September 1999

Graphite oxide, a pseudo-two-dimensional solid in bulk form, was synthesized from natural graphite powder byoxidization with KMnO44 in concentrated H24SO44. The poly(vinyl acetate)-intercalated graphite oxide nano-composite wasprepared by an in situ intercalative polymerization reaction, in which n-octanol-graphite oxide intercalation compounds werefirst obtained, vinyl acetate monomer was then dispersed into the interlayer of modified graphite oxide, followed by thermal polymerization of the monomer.It was experimentally shown that the c-axis space of poly(vinyl acetate)-intercalated graphite oxide was increased to 0.115 nm,which suggested there existed a monolayer of poly(vinyl acetate) chain between the layers of graphite oxide.The nanocomposite was also characterized with thermal analysis and FT-IR spectrometry.
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