Citation: Xiao Bang DUAN, Guo Ping CAI, William P. WEBER, Ping LU. Synthesis and Fluorescence of alt-Copoly [1,4-divinylenebenzene/1,4-bis (dimethylsilylene) benzene][J]. Chinese Chemical Letters, ;2005, 16(3): 405-408. shu

Synthesis and Fluorescence of alt-Copoly [1,4-divinylenebenzene/1,4-bis (dimethylsilylene) benzene]

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027;
2.
K. B. and D. P. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA

Received Date: 8 March 2004

Fund Project: Ping Lu thanks the National Natural Science Foundation of China (20074032, 20374045) and Ministry of Education of China for financial support.

Silicon inserted π conjugated copolymer was synthesized by Heck reaction with moderate molecular weight. This silicon containing copolymer is thermally stable to 400℃, while emission of this polymer is blue-shifted compared with polyphenylenevinylene greenish emission. It shows potential application as organic emitter in OLED.
- Silicon containing polymer,
- Heck reaction,
- photoluminescence.
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