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Citation: Jin Dan, Zhao Zhigang, Meng Han, Huang Congying, Fang Mougui. Synthesis, Structure and Optical Property of a New Pyridinium Salt[J]. Chemistry, ;2019, 82(8): 758-761. shu

Synthesis, Structure and Optical Property of a New Pyridinium Salt

School of Pharmacy, Wannan Medical College, Wuhu 241002

Received Date: 22 February 2019
Revised Date: 12 April 2019

A new compound, 4-[2-(3,4-dimethoxyphenyl)ethenyl]-N-methylpyridinium perchlorate, was synthesized by the reaction of pyridinium salt with 3,4-dimethoxybenzaldehyde in methanol. The structure of the compound was determined by IR, elemental analysis, ¹H NMR and ESI-MS. The crystal structure of the compound was further determined by X-ray single crystal diffraction. The crystal belongs to orthorhombic system with space group P_bca, a=13.5897(11)nm, b=13.9126(11)nm, c=17.3485(14)nm, α=90°, β=90°, γ=90°, M_r=355.76,V=3280.0(5)nm³, Z=8, F(000)=1488,D_c=1.181 g/cm³, μ=0.265mm^-1. Meanwhile, the optical property of the titled compound was also studied.
- Pyridinium salt,
- Synthesis,
- Crystal structure,
- Optical property
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
1. [1]
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