Citation: Shi Guo SUN, Xiao Jun PENG, Yong Qian XU, Lei SHI, Yun Ling GAO, Li Cheng SUN. Studies of a Series of Novel Rhenium(Ⅰ) Bipyridyl Dyes for Solar Cells[J]. Chinese Chemical Letters, ;2005, 16(5): 677-680. shu

Studies of a Series of Novel Rhenium(Ⅰ) Bipyridyl Dyes for Solar Cells

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Received Date: 19 April 2004

Fund Project: The authors would like to thank the National Natural Science Foundation of China (project 20128005, 20376010), the Ministry of Science & Technology and the Ministry of Education for financial support.

A series of novel rhenium(Ⅰ) 2,2'-bipyridyl complexes[fac-Re(4,4'-di-COOEt-bpy)-(CO)₃(Xpy)PF₆], where bpy is 2,2'-bipyridine, py is pyridine and X is 3-methyl, 3-hydroxy, or3-amino, were synthesized, their photophysical and electrochemical properties were studied. The Re(Ⅱ/Ⅰ) oxidation potentials decreased as the X group becomes more electron donating from H to3-methyl, 3-hydroxy, or 3-amino, which might be a very convenient ways for adjusting the electron transfer driving force.
- Rhenium(Ⅰ) bipyridyl complex,
- redox potential,
- electron transfer driving force
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