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ZHANG Tingli, HU Rongzu, ZHANG Mingnan, WANG Yaping, LIANG Yanjun, WANG Yuan. THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E[J]. Chinese Journal of Polymer Science,
;1991, 9(1): 19-23.
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The polymerization thermokinetics of pyrrole in the presence of iron trichloride art studied by using a Calvet microcalorimoter. The apparent activation energy, the pre-exponential constant and reaction order of this reaction in the temperature range of 25.2—37℃ are 34.5 KJ·mol-1, 10-1S2.74 and 1 respectively. The activation free-energies of this reaction at 25.2°, 30°and 37℃ are 91.8, 92.9 and 94.2 KJ·mol-1 respectively.
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