Citation: SHI Zhang-ping, QI Xiao-lan, LI Xu-guang, LI Hua-ying, LI Jing-qiu, KONG De-jin, YU Jun. Effect of La₂O₃ addition on the catalytic performance of Rh/SiO₂ for CO hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 483-489. shu

Effect of La₂O₃ addition on the catalytic performance of Rh/SiO₂ for CO hydrogenation

SHI Zhang-ping ^1,2 ,
QI Xiao-lan ² ,
LI Xu-guang ² ,
LI Hua-ying ² ,
LI Jing-qiu ² ,
KONG De-jin ^2,, ,
YU Jun ^1,,

1.
Research Institute of Applied Catalysis, School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, China
2.
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, SINOPEC Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China

Corresponding author: KONG De-jin, kongdj.sshy@sinopec.com YU Jun, yujun@sit.edu.cn
Received Date: 22 November 2019
Revised Date: 9 March 2020

Fund Project: the National Natural Science Foundation of China 21808142The project was supported by the National Natural Science Foundation of China (21808142)

Figures(5)

SiO₂ and La₂O₃-SiO₂ were synthesized via sol-gel method and used as support to prepared Rh-La or Rh doped catalysts by iso-volumic impregnation. Effects of doping mode of La on the catalytic performance of Rh/SiO₂ for CO hydrogenation are investigated detailedly. The results reveal that the addition of La can improve the dispersion of Rh and increase Rh⁺ centers, which can effectively inhibit the formation of CO₂ and improve the selectivity of oxygenates. Furthermore, the doping mode of La can affect the interaction between La and Rh. A strong La-Rh interaction is achieved over the 2Rh-5La₂O₃/SiO₂ catalyst prepared by co-impregnation of Rh and La with SiO₂ support. The strong interaction between La and Rh can efficiently weaken the Rh-CO bonds and enhance the CO insertion reaction in the reaction process, which makes the product dominated by C₂₊ oxygenates. The 2Rh/5La₂O₃-SiO₂ catalyst prepared via La₂O₃-SiO₂ composite support exhibits a weak La-Rh interaction, and methanol, ethanol and other low-carbon alcohols are obtained as the main products.
- La₂O₃ addition,
- Rh/SiO₂ catalyst,
- CO hydrogenation,
- C₂ oxygenates
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Effect of La₂O₃ addition on the catalytic performance of Rh/SiO₂ for CO hydrogenation