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Citation: Wang Yu, Zhang Lipeng, Zhao Yuxia. Study on the Relationship of Structures and Spectral Properties of Aromatic Ketone Derivatives with Twisted Intramolecular Charge Transfer[J]. Chemistry, ;2019, 82(7): 612-617. shu

Study on the Relationship of Structures and Spectral Properties of Aromatic Ketone Derivatives with Twisted Intramolecular Charge Transfer

Wang Yu ^1,2 ,
Zhang Lipeng ¹ ,
Zhao Yuxia ^1,,

1.
Technical Institute of Physics and Chemistry, CAS, Beijing 100190
2.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Zhao Yuxia, yuxia.zhao@mail.ipc.ac.cn
Received Date: 11 March 2019
Accepted Date: 9 April 2019

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A series of compounds with twisted intramolecular charge transfer (TICT) based on aromatic ketone derivatives were synthesized and characterized. The effects of different conjugated groups and substituent positions on the spectral properties of these compounds were studied by characterization of their linear photophysical and two-photon absorption properties. Additionally, the intramolecular charge transfer properties of these compounds were also studied by solvent effect. Combined with theoretical calculations, the results showed that the molecular conjugated skeleton and the position of substituents can significantly affect the intramolecular charge transfer characteristics. Fluorenone based compounds exhibite strong two-photon absorption and aggregation-induced fluorescence enhancement effects, which have potential applications in biological imaging.
- Intramolecular charge transfer,
- Two photon absorption,
- Fluorescence,
- Aggregation-induced emission,
- Biological imaging
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