Citation: Yi Min SHE, Ya Ping TU, Xing Hua GUO, Zi Yang LIU, Shu Ying LIU. REACTIONS OF C₆₀ WITH R₃SnH:A NEW SYNTHETIC TO C₆₀(RH)_n AND THE PROPERTY OF C₆₀ TO CATALYZE RADICAL REACTIONS[J]. Chinese Chemical Letters, ;1996, 7(5): 433-436. shu

REACTIONS OF C₆₀ WITH R₃SnH:A NEW SYNTHETIC TO C₆₀(RH)_n AND THE PROPERTY OF C₆₀ TO CATALYZE RADICAL REACTIONS

Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun, 130022

Received Date: 3 November 1995

Fund Project: We thank the National Natural Science Foundation and the Laboratoty of Applied Spectroscopy for financial support of this work. We are also grateful to Professor Fangxin Fu of Northeast Normal University for providing the organic tin materials.

A new method for the preparation of polyalkyl and polyarenefullerene derivatives C₆₀(RH)_n (R=Bu,n=1-3;R=Ph,n=1-10) by the reaction of C₆₀ with organotin hydride in toluene is described.Another series of products of stannanes R_aSn_bH_c (R=Bu,a=3-8,b=1-4,c=0-3;R=Ph,a=3-11,b=1-5,c=0-4) were also obtained,which shows that C₆₀ can catalyze polymerization of organic-tin.These products were determined by mass and infrared spectrometry.And the possible reaction mechanisms are discussed.
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