Citation: Jian Kui ZHAO, Yan Guang WANG. A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides[J]. Chinese Chemical Letters, ;2002, 13(12): 1149-1151.
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Catalytic amination of aryl bromides with in situ generated dimethylamines from N,N-dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aromatic system reacted smoothly under the conditions to give N,N-dimethylarylamines in good yields.
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