Citation: LIU Shijie, ZHANG Xiqi, JIANG Lei. Nanoconfined Ordered-Assembly Reaction[J]. Chinese Journal of Catalysis, ;2019, 40(s1): 17-25. shu

Nanoconfined Ordered-Assembly Reaction

LIU Shijie ^1,2, ,
ZHANG Xiqi ¹ ,
JIANG Lei ^1,2,3

1.
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
2.
School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
3.
Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing 100191, China

Fund Project: This work was supported by the National Natural Science Foundation of China (51603211, 51673107) and National Key R&D Program of China (2016YFA0200803).

Nanoconfined chemical reactions in different dimensions generally exhibit enhanced performance, as a consequence of nanoconfinement, yet the inherent mechanism of this nanoconfinement-enhanced performance remains elusive. Here, our perspectives on nanoconfined chemical reactions are first provided, followed by nanoconfined pre-assembled reactions. Then, ultrafast mass transport behaviors in biological and artificial nanochannels are discussed and the quantum-confined superfluid concept is introduced. Inspired by the pro-grammed-assembly reaction in living organisms, a new concept of ordered-assembly reaction is proposed through combining quan-tum-confined superfluid with frontier molecular orbital theory, to understand the inherent mechanism of high-performance nanoconfined chemical reactions. Finally, the prospective for future development of the ordered-assembly reaction concept is presented.
- nanochannels,
- nanoconfinement,
- quantum-confined superfluid,
- frontier molecular orbital theory,
- ordered-assembly reaction
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