Citation: ZHANG Yifeng, CAI Yiping, YANG Mujie, SHEN Zhiquan. THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*[J]. Chinese Journal of Polymer Science, ;1985, 3(4): 367-372. shu

THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*

Received Date: 28 July 1985

This paper describes the polymerization of acetylene by coordination catalysts composed ofvarious neodymium compounds, (Nd (P204)3; Nd (P507)3; Nd (NO3)3 3P350; Nd (BA)3.2H2O; and Nd (acac)3.2H2O), aluminum trialkyl and an electron donor. The catalysts show fairly high catalyticactivity and high cis stereospecificity on acetylene polymerization at 30℃.
1. [1]
  Jingfeng Yue , Zhenxin Tang , Yuxing Zhang , Zhongbao Jian . Oligomeric α-diimine nickel catalysts for enhanced ethylene polymerization. Chinese Chemical Letters, 2026, 37(1): 111930-. doi: 10.1016/j.cclet.2025.111930
2. [2]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
3. [3]
  Heng Gao , Zhaocong Cheng , Guangshui Tu , Zonglin Qiu , Xieyi Xiao , Haotian Zhou , Handou Zheng , Haiyang Gao . Thermally robust bis(imino)pyridyl iron catalysts for ethylene polymerization: Synergy effects of weak π-π interaction, steric bulk, and electronic tuning. Chinese Chemical Letters, 2025, 36(5): 110762-. doi: 10.1016/j.cclet.2024.110762
4. [4]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415
5. [5]
  Li-Min Cui , Wei-Hui Fang , Jian Zhang . Polyoxometalates containing aluminum atoms. Chinese Chemical Letters, 2025, 36(10): 110386-. doi: 10.1016/j.cclet.2024.110386
6. [6]
  Tianjun Ni , Hui Zhang , Liping Zhou , Roujie Ma , Yanyu Wang , Zhijun Yang , Dan Luo , Nithima Khaorapapong , Xingtao Xu , Yusuke Yamauchi , Dong Liu . Atomic cobalt catalysts on 3D interconnected g-C₃N₄ support for activation of peroxymonosulfate: The importance of Co-N coordination effect. Chinese Chemical Letters, 2025, 36(9): 110659-. doi: 10.1016/j.cclet.2024.110659
7. [7]
  Huiying LIN , Xiang ZHAO , Banghao WEI , Bufeng WANG , Zhiyong LU , Junfeng BAI . Perfluroalkane functionalization on MOF-808 for acetylene purification. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2103-2114. doi: 10.11862/CJIC.20250110
8. [8]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
9. [9]
  Xiaoqian Wei , Hanyu Gao , Tiantian Wang , Zijian Li , Yanru Geng , Guiping Zheng , Min Gyu Kim , Haeseong Jang , Xien Liu , Qing Qin . Neodymium-doped hollow Ir/IrO2 nanospheres with low geometric iridium density enable excellent acidic water oxidation performance. Chinese Journal of Structural Chemistry, 2025, 44(7): 100600-100600. doi: 10.1016/j.cjsc.2025.100600
10. [10]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
11. [11]
  Lixing LU , Shaoxian LIU , Jian XU , Ziqi JIN , Jiongjia CHENG , Jiyang ZHAO , Fubo WANG , Haiying WANG . [FeFe]-hydrogenase-containing compound and its photocatalytic H₂-production performance. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2584-2590. doi: 10.11862/CJIC.20250200
12. [12]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
13. [13]
  Tianyang Dong , Xingyuan Wen , Xingzhi Wu , Ying Jiang , Chong Wang , Ruizhi Liu , Junyi Li , Wenfa Zhou , Yinglin Song , Xiaofeng Shi , Rui Wen , Chunru Wang , Li Jiang , Chunli Bai . Ionic covalent organic frameworks enable laser-pulse-duration-dependent high third-order nonlinear optical responses. Chinese Journal of Structural Chemistry, 2025, 44(10): 100733-100733. doi: 10.1016/j.cjsc.2025.100733
14. [14]
  Shifang Song , Chenyu Wu , Li Zhang , Dezhi Yang , Yang Lu , Zhengzheng Zhou . Unpacking phase transitions in multi-component drug systems: A case study. Chinese Chemical Letters, 2025, 36(7): 110911-. doi: 10.1016/j.cclet.2025.110911
15. [15]
  Zhi-Peng Bao , Hefei Yang , Ru-Han A , Yuanrui Wang , Xiao-Feng Wu . Carbonylative five-component synthesis of amides and esters with α-quaternary carbon center. Chinese Chemical Letters, 2025, 36(11): 111150-. doi: 10.1016/j.cclet.2025.111150
16. [16]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
17. [17]
  Jing Guo . Stacking solid-state electrolyte and aluminum pellets for anode-free solid-state batteries. Chinese Chemical Letters, 2025, 36(5): 110764-. doi: 10.1016/j.cclet.2024.110764
18. [18]
  Jun Li , Shi-Hu Du , Yao Zhang , Jia Liu , Jing Chen , Shi-Bo Cheng . Shell-independent superhalogen formation in aluminum-based clusters via boron Lewis acid ligands functionalization. Chinese Chemical Letters, 2026, 37(1): 111177-. doi: 10.1016/j.cclet.2025.111177
19. [19]
  Gen Zhang , Ying Gu , Lin Li , Fuli Ma , Dan Yue , Xiaoguang Zhou , Chungui Tian . Anion-modulated HER and OER activity of 1D Co-Mo based interstitial compound heterojunctions for the effective overall water splitting. Chinese Chemical Letters, 2025, 36(7): 110110-. doi: 10.1016/j.cclet.2024.110110
20. [20]
  Wenrui Jia , Chenghuan Qiao , Dongfang Zhao , Juanshan Du , Yaohua Wu , Yongqi Liang , Qinglian Wu , Xiaochi Feng , Huazhe Wang , Wanqian Guo . Insight into nitrogen-doped biochar prepared from Chinese medicine compound residue for peracetic acid activation in sulfamethoxazole degradation: Electron transfer mechanism. Chinese Chemical Letters, 2025, 36(11): 110886-. doi: 10.1016/j.cclet.2025.110886

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1252)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return