Citation: Qian Kun ZHUANO, Xiao Xia GAO. INVESTIGATION ON THE WATER-SOLUBLE YTTERBIUM PORPHYRIN PART I．SYNTHESIS，COMPOSITION AND STRUCTURE[J]. Chinese Chemical Letters, ;1995, 6(2): 147-148. shu

INVESTIGATION ON THE WATER-SOLUBLE YTTERBIUM PORPHYRIN PART I．SYNTHESIS，COMPOSITION AND STRUCTURE

Department of Chemistry, Peking University, Beijing, 100871

Received Date: 23 August 1994

Fund Project: This project was supported by the National Natural Science Foundation of China. The authors are grateful to Prof.Wu Jineuang for her skillful help in the assienment of IR bands in Table 1.

Water-soluble ytterbium complex of tetra-p-sulfonatophenylporphyrin(H₂TPPS)with the formulation Yb·TPPS·OH·2 im·3H₂O(im=imidazole),stable in pH≥5 solution,has been synthesized and characterized by elemental analysis,IR and electronic absorption spectroscopy.Its structure is also proposed.The ytterbium atom exhibits a coordination number of seven with the ytterbium atom out of the porphyrin plane.
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