Citation: Qi Tao LIU, Xiang Dong ZHANG, Wei GUAN, Jin Yu SUN. STRUCTURAL EVIDENCE FOR THE METAL ION BRIDGED LIGAND-LIGAND INTERACTION:THE X-RAY CRYSTAL STRUCTURE OF [(2，2'-BIPYRIDYL)(PHENYLMALONATE)COPPER(Ⅱ)] TRIHYDRATE[J]. Chinese Chemical Letters, ;1996, 7(3): 263-264. shu

STRUCTURAL EVIDENCE FOR THE METAL ION BRIDGED LIGAND-LIGAND INTERACTION:THE X-RAY CRYSTAL STRUCTURE OF [(2，2'-BIPYRIDYL)(PHENYLMALONATE)COPPER(Ⅱ)] TRIHYDRATE

Department of Chemistry, Liaoning University, Shenyang 110036

Received Date: 28 August 1995

Fund Project: This work is supported by the National Natural Science Foundation of China.

The crystal structure of the ternary complex [Cu(L)(2,2'-bipy)H₂O]·₂H₂O (L=phenylmalonate) has been determined by X-ray diffraction methods.The copper(Ⅱ) center in five-coordinate square-pyramidal structure.It is of interest in this structure that the complex involves a metal ion bridge ligand-ligand aromatic ring stacking interaction.
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