Citation: Feng SHI, Hong Yang LI, Xiao Jun PENG, Rong ZHANG, Xiao Qiang CHEN, Jiang Li FAN, Li Cheng SUN. Synthesis and Photochemical Properties of a New Substituted Phenol Covalently Linked to Ruthenium (Ⅱ) Tris-bipyridine Containing Four Ester Groups as Sensitizer[J]. Chinese Chemical Letters, ;2004, 15(12): 1407-1410. shu

Synthesis and Photochemical Properties of a New Substituted Phenol Covalently Linked to Ruthenium (Ⅱ) Tris-bipyridine Containing Four Ester Groups as Sensitizer

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Received Date: 20 October 2003

Fund Project: This work was supported by "973 program" of the Ministry of Science and Technology of China and the National Natural Science Foundation of China (Project 20376010,20128005).

As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied.
- Photosensitizer,
- ruthenium complex,
- phenolate ligand,
- nanocryatalline TiO₂,
- solar cell
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