Citation: Xiu Mei ZHANG, Long CHENG, Xian Dan XI, Bai Feng LIU, Shao Jun Dong. ELECTROCHEMICAL BEHAVIOR OF MOLYBDOTUNGSATE HETEROPOLY COMPLEX WITH NEODYMIUMK₁₀H₃[Nd(SiMO₇W₄O₃₉)₂]xH₂0 IN AQUEOUS SOLUTION[J]. Chinese Chemical Letters, ;1996, 7(1): 81-84. shu

ELECTROCHEMICAL BEHAVIOR OF MOLYBDOTUNGSATE HETEROPOLY COMPLEX WITH NEODYMIUMK₁₀H₃[Nd(SiMO₇W₄O₃₉)₂]xH₂0 IN AQUEOUS SOLUTION

1.
Department of Chemistry, Harbin Engineering University, Harbin, 150001;
2.
Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry. ChineseAcademy of Sciences, Changchun, 130022

Received Date: 26 July 1995

The voltammetric behavior of the titled compound (denoted as Nd (SiMo₇W₄)₂^13-) in aqueous solution had been studied.An unusual pH response was discussed.The adsorption of the anion on the dropping mercury electrode and a selfinhibition influence of the adsorbed anions on the redox process of those anions dissolved in solution were found.The electrocatalytic effects of the anion on the bromate reduction were investigated.
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