Citation: Yun Xing YAN, Qi FANG, Wen Tao YU, Yu Peng TIAN, Duo Rong YUAN, Xin Qiang WANG, Fan Qing MENG, Zhi Gang CAI, Ling Zhi ZHANG. Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate[J]. Chinese Chemical Letters, ;1998, 9(12): 1125-1128. shu

Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate

1.
Institute of Crystal Materials and State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100;
2.
Institute of Laser Spectroscopy and Stake Key Laboratory of Ultrafast Laser Spectroscopy, Zhongshan University, Guangzhou, 510275

Received Date: 20 April 1998

Fund Project: This work was supported by the National Natural Science Foundation of China and by the Scientific Research Foundation for Outstanding Young Scientist of Shangdong Province of China.

Iron Mercury Tetrathiocyanate (FeHg(SCN)₄) has been synthesized and its structure has been determined. It belongs to the tetragonal system, 14 space group. The Hg-S-C≡N-Fe bridge leads to the formation of an infinite three dimensional network. Irradiated by a 1.064 nm Nd:YAG laser beam, FeHg (SCN)₄ showed a 0.532 nm second harmonic intensity which is 0.6 times as that of organic nonlinear optical crystal urea.
- FeHg(SCN)4,
- synthesis,
- structure,
- nonlinear property
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