Citation: Guo Bin RONG, Ru Jian MA, Chong Ying ZHOU, Zhu Liang JIN, Wan Nian WU, Qing WANG. The Preparation of Unsymmetrical Diaminodimethylsilanes and the Cleavage of Silicon-Nitrogen Bonds by Acid Chloride[J]. Chinese Chemical Letters, ;1997, 8(11): 945-946. shu

The Preparation of Unsymmetrical Diaminodimethylsilanes and the Cleavage of Silicon-Nitrogen Bonds by Acid Chloride

Department of Chemistry, East China University of Science and Technology, Shanghai, 200237

Received Date: 2 July 1997

Fund Project: This work was supported by the National Natural Science Foundation of China.

Seven unsymmetrical diaminodimethylsilanes were prepared.The reactions of these silylamine with benzoyl chloride indicated that in comparison with electronic,the steric effect played more important role on the reactivity of Si-N bond.As a new method,unsymmetrical diamide can be produced by the reaction of the title compounds with diacid chloride.
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