Citation: Zhi LIU, Qi FANG, Wen Tao YU, Min Hua JIANG, De Qing ZHANG, Dao Ben ZHU. Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O[J]. Chinese Chemical Letters, ;2003, 14(4): 433-436. shu

Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2.
Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080

Received Date: 27 May 2002

Fund Project: This project was supported by a grant for the State Key Program of China and by the National Natural Science Foundation of China (No.20172034), and also supported by the open laboratory of organic solid of Institute of Chemistry of the Chinese Academy of Sciences.

Electro-oxidation of 3,4,3', 4(-bis(ethylenedithio)-2,2',5,5(-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O. The single crystal structure of the title compound is determined to be in orthorhombic crystal system, Pma2 space group. This salt is a semiconductor and its room-temperature conductivity is 0.0489Ω^-1·m^-1.
- ET,
- electro-oxidation,
- crystal structure,
- conductivity
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