Citation: Ming Ming MIAO, Dai Zheng LIAO, Zone Hui JIANG, Geng Lin WANG. FERROMAGNETICALLY COUPLED Gd (Ⅲ)Cu (Ⅱ)Gd (Ⅲ)TRINUCLEAR COMPLEXES[J]. Chinese Chemical Letters, ;1995, 6(6): 533-536. shu

FERROMAGNETICALLY COUPLED Gd (Ⅲ)Cu (Ⅱ)Gd (Ⅲ)TRINUCLEAR COMPLEXES

Department of Chemistry, Nankai University, Tianjin, 300071

Received Date: 17 October 1994

Fund Project: This paper was supported by the National Natural Science Foundation of China.

Three new heterotrinuclear complexes have been synthesized and characterized, namely {[Gd(L)₂]₂ [Cu (pbaOH)]} (ClO₄)₄, where pbaOH denotes 2-hydroxy-1, 3-propylenebis(oxamato), L stands for 1, 10-phenanthroline (phen), 5-nitro-1, 10-phenan-throline (NO₂-phen) or 2, 2'-bipyridyl (bpy).The temperature dependence of the magnetic susceptibility of {[Gd(phen)₂ (ClO₄)₂]₂ [Cu (pbaOH)]} (ClO₄)₂ has been studied in the 4-300K range, giving the exchange integral J=6.69 cm^-1.This indicates a weak ferromagnetic interaction between the copper(Ⅱ) and gadolinium (Ⅲ) ions.
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