Citation: Feng SHI, Hong Yang LI, Xiao Jun PENG, Rong ZHANG, Xiao Qiang CHEN, Jiang Li FAN, Jing Nan CUI, Björn Åkermark, Li Cheng SUN. Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups[J]. Chinese Chemical Letters, ;2005, 16(1): 89-92. shu

Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012;
2.
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden;
3.
Department of Chemistry, Organic Chemistry, Royal Institute of Technology (KTH), 100 44 Stockholm, Sweden

Received Date: 18 November 2003

Fund Project: This work was supported by "973 program" of the Ministry of Science and Technology of China, the National Naturd Science Foundation of China (Project 20376010, 20128005), B. Å. and L. S. thank the Swedish Energy Agency and the Swedish Research Council for financial support.

Two novel high valent complexes [M₂(Ⅲ, Ⅲ)L(μ-OAc)₂]·PF₆(M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl) (pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn₂(Ⅱ, Ⅱ) (bpmp) (μ-OAc₂)·CLO₄ (10).These improvements decreascd the difference beteween the mew mode and (Mn)₄ cluster (OEC in nature).
- Dinuclear complex,
- OEC,
- artificial photosynthesis.
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