Citation: Bao Yu XUE, Zhen Feng Xi, Si Guo YUAN, Dou Man JIN. PRELIMINARY STUDIES ON THE SYNTHESIS AND CHARACTERIZATION OF OXY-AND THIO-DIACETIC ACID HYDRAZITION AND THEIR FIRST-ROW TRANSITION METAL COMPLEXES[J]. Chinese Chemical Letters, ;1991, 3(9): 725-726. shu

PRELIMINARY STUDIES ON THE SYNTHESIS AND CHARACTERIZATION OF OXY-AND THIO-DIACETIC ACID HYDRAZITION AND THEIR FIRST-ROW TRANSITION METAL COMPLEXES

Henan Institute of Chemistry Zhengzhou 450003

Received Date: 27 May 1991

It has been made certain that thio-and oxy-diacetic acid hydrazides are potential anticancer compounds^[1.2].However, their ability to form complexes with transition metals and the properties of the complexes thus formed have not been studied.Employing a new potential anticancer ligand 1, 2-bis（thioacetic acid hydrazide）ethane prepared in our lab, along with ligands oxydiacetic hydrazide and 1, 2-bis（oxyacetic acid hydrazide）ethane, a series of 11 new first-row transition metal(M=Zn²⁺, Cu²⁺, Co²⁺, Ni²⁺)complexes with each of the above three ligands have been synthesized and characterized by means of elemental analyses, IR, TG and X-ray powder diffraction.
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