Citation: Qing Ping HU, Xue GuI CUI, Zhao He YANG. STUDIES ON THE NON-ISOTHERMAL KINETICS OF THERMAL DECOMPOSITIONS OF THE COMPLEXES OF Cd(Ⅱ)WITH O-VANILLIN THIOSEMICARBAZONE AND IRON(Ⅲ)WITH 2-(O-HYDROXYBENZYLIDENE)AMINO]PHENOL AND PYRIDINE[J]. Chinese Chemical Letters, ;1995, 6(7): 637-640. shu

STUDIES ON THE NON-ISOTHERMAL KINETICS OF THERMAL DECOMPOSITIONS OF THE COMPLEXES OF Cd(Ⅱ)WITH O-VANILLIN THIOSEMICARBAZONE AND IRON(Ⅲ)WITH 2-(O-HYDROXYBENZYLIDENE)AMINO]PHENOL AND PYRIDINE

a Department of Chemistry, Shandong University, Jinan 250100;
b Inst. of Crys. Mat., Shandong University, Jinan 250100

Received Date: 5 January 1995

Fund Project: The project was supported by National Laboratory of Crystal Materials, Shandong University Fundation.

The thermal decompositions of the complex of Cd(Ⅱ)with o-vanillin thiosemicarbazone(complex 1)and the mixed ligand complex of iron(Ⅲ)with 2-[(o-hydroxybenzylidene)amino]phenol and pyridine(complex 2)and their non-isothermal kinetics have been studied by TG and DTG techniques.The non-isothermal kinetic data were analyzed and the kinetic parameters for the first and second steps of the thermal decompositions were evaluated by two different methods——differential and integral methods.Their kinetic equations were obtained.
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