Citation: You Gang MAO, Rui Fang SONG, Jia Cong SHEN. THE STUDY OF ESR SPECTRA IN SOLID STATR AND HIGH VISCOSITY SOLUTION FOR PROPAGATING RADICAL OF POLYSTYRRNE[J]. Chinese Chemical Letters, ;1994, 5(8): 695-696. shu

THE STUDY OF ESR SPECTRA IN SOLID STATR AND HIGH VISCOSITY SOLUTION FOR PROPAGATING RADICAL OF POLYSTYRRNE

Key Laboratory for Molecular Spectra & Structure, Institute of Theoretical Chemistry, Jilin University, Jilin University, Changchun, 130023

Received Date: 27 May 1994

In this paper,The 3-line in solid and 12-line high-viscosity solution ESR spectra of the propagating radical of Polystyrene were studied.The 3-line spectrum comes from the conformation of the radical R1 which usually corresponds to a 6-line typical spectrum but appear as an apparent 3-line spectrum in solid state.The 12-line spectrum comes from two species of radicals with the same confomation R2 but different G factor.R2 corresponds to a 8-line typical spectrum which appear as an apparent 6-line spectrum in the high-viscosity solution.Therefore,two apparent 6-line spectra of R2 with different g values form the 12-line spectrum.
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