Citation: Wei Ming XU, You Chu ZHANG, Xian HUANG. Polystyrene-supported Selenides and Selenoxide:Versatile Routes to Synthesize Allylic Alcohols[J]. Chinese Chemical Letters, ;2003, 14(8): 797-799. shu

Polystyrene-supported Selenides and Selenoxide:Versatile Routes to Synthesize Allylic Alcohols

1.
Department of Chemistry, Zhejiang University(Xixi Campus), Hangzhou 310028;
2.
Department of Chemistry, Shaoxing College of Arts and Sciences, Shaoxing 312000

Received Date: 8 October 2002

Fund Project: Project 29932020 was supported by the National Natural Science Foundation of China.

Several polystyrene-supported selenides and selenoxide have been prepared firstly. These novel reagents were treated with LDA to produce selenium stabilized carbanions, which reacted with aldehydes and alkyl halides, followed by selenoxide syn-elimination and [2,3] sigmatropic rearrangement respectively to give Z-allylic alcohols stereoselectively.
- Solid phase synthesis,
- selenides and selenoxide,
- allylic alcohol
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