Citation: Hongwei Lv, Min Chen, Huang Zhou, Yuen Wu. Progress in Ultra-Stable Single-Atom Catalysts with Sintering Resistance[J]. Chemistry, ;2021, 84(1): 2-9, 30. shu

Progress in Ultra-Stable Single-Atom Catalysts with Sintering Resistance

School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, 230026

Corresponding author: Yuen Wu, yuenwu@ustc.edu.cn
Received Date: 24 August 2020
Accepted Date: 25 September 2020

Figures(6)

Traditional supported metal catalysts are prone to sintering under high temperature environments or after long hours of work. This irreversible process will result in a significant reduction of the active sites of the catalysts, which will cause the catalysts to be severely deactivated. Therefore, it is often necessary to update the catalysts in time to meet the needs of industrial production, but this will greatly increase production costs. Unlike traditional supported metal catalysts, the central metal atom of single-atom catalysts (SACs) can form strong bonds with heteroatoms (N, O, S, etc.), thereby effectively inhibiting metal sintering. Based on the characteristics of single-atom catalysts, we can prepare ultra-stable single-atom catalysts that are resistant to sintering and high temperature to deal with special industrial catalytic environments. This paper summarizes the progress in the synthesis and application of anti-sintering ultra-stable single-atom catalysts in recent years, and provides references for the research in the field of single-atom catalysis.
- Supported metal catalysts,
- Single-atom catalysts,
- Sintering resistance,
- Synthesis and application
1. [1]
  Noyori R. Nat. Chem., 2009, 1(1): 5~6.
2. [2]
  Xu Z, Xiao F S, Purnell S K, et al. Nature, 1994, (372): 346~348.
3. [3]
  Dai Y, Lu P, Cao Z, et al. Chem. Soc. Rev., 2018, 47(12): 4314~4331.
4. [4]
  Qiao B, Wang A, Yang X, et al. Nat. Chem., 2011, 3(8): 634~641.
5. [5]
  Jiang R, Li L, Sheng T, et al. J. Am. Chem. Soc., 2018, 140(37): 11594~11598.
6. [6]
  Chen F, Jiang X, Zhang L, et al. Chin. J. Catal., 2018, 39(5): 893~898.
7. [7]
  Zhuang Z, Kang Q, Wang D, et al. Nano Res., 2020, 13(7): 1856~1866.
8. [8]
  Zhang J, Zheng C, Zhang M, et al. Nano Res., 2020, 13(11): 3082~3087.
9. [9]
  Yang X, Wang A, Qiao B, et al. Acc. Chem. Res., 2013, 46(8): 1740~1748.
10. [10]
  Vajda S, White M G. ACS Catal., 2015, 5(12): 7152~7176.
11. [11]
  Boronat M, Leyva-Pérez A, Corma A. Acc. Chem. Res., 2014, 47(3): 834~844.
12. [12]
  Corma A, Concepcion P, Boronat M, et al. Nat. Chem., 2013, 5(9): 775~781.
13. [13]
  Zhang X, Sun Z, Wang B, et al. J. Am. Chem. Soc., 2018, 140(3): 954~962.
14. [14]
  Zhu C, Fu S, Shi Q, et al. Angew. Chem. Int. Ed., 2017, 56(45): 13944~13960.
15. [15]
  Liu L, Corma A. Chem. Rev., 2018, 118(10): 4981~5079.
16. [16]
  Yao Y, Huang Z, Xie P, et al. Nat. Nanotechnol., 2019, 14(9): 851~857.
17. [17]
  Sun T, Xu L, Wang D, et al. Nano Res., 2019, 12(9): 2067~2080.
18. [18]
  Li X, Rong H, Zhang J, et al. Nano Res., 2020, 13(7): 1842~1855.
19. [19]
  Zhang H, Wei J, Dong J, et al. Angew. Chem. Int. Ed., 2016, 55(46): 14310~14314.
20. [20]
  Yin P, Yao T, Wu Y, et al. Angew. Chem. Int. Ed., 2016, 55(36): 10800~10805.
21. [21]
  Wang X, Chen Z, Zhao X, et al. Angew. Chem. Int. Ed., 2018, 57(7): 1944~1948.
22. [22]
  Wang J, Huang Z, Liu W, et al. J. Am. Chem. Soc., 2017, 139(48): 17281~17284.
23. [23]
  Zhao Y, Zhou H, Chen W, et al. J. Am. Chem. Soc., 2019, 141(27): 10590~10594.
24. [24]
  Jones J, Xiong H, De La Riva A T, et al. Science, 2016, 353(6295): 150~154.
25. [25]
  Qu Y, Li Z, Chen W, et al. Nat. Catal., 2018, 1(10): 781~786.
26. [26]
  Yang Z, Chen B, Chen W, et al. Nat. Commun., 2019, 10(1): 3734.
27. [27]
  Zhao C, Wang Y, Li Z, et al. Joule, 2019, 3(2): 584~594.
28. [28]
  Yang Z, Zhao C, Qu Y, et al. Adv. Mater., 2019, 31(12): 1808043.
29. [29]
  Wei S, Li A, Liu J C, et al. Nat. Nanotechnol., 2018, 13(9): 856~861.
30. [30]
  Zhou H, Liu T, Zhao X, et al. Angew. Chem. Int. Ed., 2019, 58(51): 18388~18393.
31. [31]
  Zhou H, Zhao Y, Xu J, et al. Nat. Commun., 2020, 11(1): 335.
32. [32]
  Zhang B W, Sheng T, Liu Y D, et al. Nat Commun, 2018, 9(1): 4082.
33. [33]
  Zhou H, Zhao Y, Gan J, et al. J. Am. Chem. Soc., 2020, 142(29): 12643~12650.
34. [34]
  Zhang N, Ye C, Yan H, et al. Nano Res., 2020, DOI: 10.1007/s12274-020-2994-3.
35. [35]
  Herrerías C, Yao X, Li Z, et al. Chem. Rev., 2007, 107(6): 2546~2562.
36. [36]
  Cui X, Li H, Wang Y, et al. Chem, 2018, 4(8): 1902~1910.
37. [37]
  Huang W, McCormick J, Lobo R, et al. J. Catal., 2007, 246(1): 40~51.
38. [38]
  Liu Y, Liu X, Feng Q, et al. Adv. Mater., 2016, 28(23): 4747~4754.
39. [39]
  Dai X, Chen Z, Yao T, et al. Chem. Commun., 2017, 53(84): 11568~11571.
40. [40]
  Wang X, Chen W, Zhang L, et al. J. Am. Chem. Soc., 2017, 139(28): 9419~9422.
41. [41]
  Zhao C, Xiong C, Liu X, et al. Chem. Commun., 2019, 55(16): 2285~2288.
42. [42]
  Chen M, Zhou H, Liu X, et al. Small, 2020, 16(31): 2002343.
43. [43]
  Han Y, Wang Y G, Chen W, et al. J. Am. Chem. Soc., 2017, 139(48): 17269~17272.
44. [44]
  Yang Z, Wang Y, Zhu M, et al. ACS Catal., 2019, 9(3): 2158~2163.
1. [1]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
2. [2]
  Ying Chen , Ronghua Yan , Weiyan Yin . Research Progress on the Synthesis of Metal Single-Atom Catalysts and Their Applications in Electrocatalytic Hydrogen Evolution Reactions. University Chemistry, 2025, 40(9): 344-353. doi: 10.12461/PKU.DXHX202503066
3. [3]
  Zhiqiang XING , Jinling LIU , Mingmin SU , Lei ZHANG , Lijun YANG . CoNi dual-single-atom catalyst for electrocatalytic H₂O₂ production and in situ electro-Fenton degradation of pollutants. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2479-2490. doi: 10.11862/CJIC.20250181
4. [4]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
5. [5]
  Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015
6. [6]
  Chengcheng Yuan , Wei Xia , Jun Wang , Xiaofeng Zhu , Yong Zhang , Bicheng Zhu , Jiaguo Yu . A dual-functional single-atom modified SnS₂/CdS S-scheme photocatalyst for synergistic hydrogen production and lactic acid oxidation: A DFT study. Acta Physico-Chimica Sinica, 2026, 42(6): 100244-0. doi: 10.1016/j.actphy.2026.100244
7. [7]
  Lutian Zhao , Yangge Guo , Liuxuan Luo , Xiaohui Yan , Shuiyun Shen , Junliang Zhang . Electrochemical Synthesis for Metallic Nanocrystal Electrocatalysts: Principle, Application and Challenge. Acta Physico-Chimica Sinica, 2024, 40(7): 2306029-0. doi: 10.3866/PKU.WHXB202306029
8. [8]
  Kangjuan Cheng , Chunxiao Liu , Youpeng Wang , Qiu Jiang , Tingting Zheng , Xu Li , Chuan Xia . Design of noble metal catalysts and reactors for the electrosynthesis of hydrogen peroxide. Acta Physico-Chimica Sinica, 2025, 41(10): 100112-0. doi: 10.1016/j.actphy.2025.100112
9. [9]
  Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-0. doi: 10.1016/j.actphy.2025.100100
10. [10]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
11. [11]
  Haiqiang Lin , Weizheng Weng , Jingdong Lin , Mingshu Chen , Xueming Fang , Lefu Yang . Diverse Variables-Driven Catalytic Optimization: Experimental Enhancement and Instructional Design for Selective Methane Oxidation on Supported Nickel-based Catalysts. University Chemistry, 2025, 40(11): 327-336. doi: 10.12461/PKU.DXHX202505106
12. [12]
  Qi Wang , Yuqing Liu , Jiefei Wang , Yuan-Yuan Ma , Jing Du , Zhan-Gang Han . Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges. Acta Physico-Chimica Sinica, 2025, 41(10): 100120-0. doi: 10.1016/j.actphy.2025.100120
13. [13]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
14. [14]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
15. [15]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
16. [16]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
17. [17]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
18. [18]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-0. doi: 10.3866/PKU.WHXB202408004
19. [19]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
20. [20]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071

Get Citation

PDF

XML

Metrics

PDF Downloads(71)
Abstract views(2649)
HTML views(757)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142