Citation: SHI Qi-qi, GUO He-qin, CHEN Cong-biao, HOU Bo, JIA Li-tao, LI De-bao. Study on the performance of CF₃SO₃H modified sulfonic polymer-based catalyst in formaldehyde carbonylation reaction[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 875-882. shu

Study on the performance of CF₃SO₃H modified sulfonic polymer-based catalyst in formaldehyde carbonylation reaction

SHI Qi-qi ^1,2 ,
GUO He-qin ^1,, ,
CHEN Cong-biao ¹ ,
HOU Bo ¹ ,
JIA Li-tao ^1,3 ,
LI De-bao ^1,3,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Dalian National Laboratory of Clean Energy, Dalian 116023, China

Corresponding author: GUO He-qin, heqinguo@sxicc.ac.cn LI De-bao, dbli@sxicc.ac.cn
Received Date: 28 February 2020
Revised Date: 15 June 2020

Fund Project: the Key Research Project of Shanxi Province, China 201903D121033The project was supported by the Key Research Project of Shanxi Province, China (201903D121033)

Figures(7)

A sulfonic polymer-based catalyst (PDS-1.0) was synthesized by the hydrothermal and in situ sulfonation method, which is further modified by grafting with CF₃SO₃H, to get the PDS-1.0-F catalyst. The physical and chemical properties of the PDS-1.0 and PDS-1.0-F catalysts were characterized by N₂ sorption, TG, FT-IR, ³¹P MAS NMR and XPS; the effect of CF₃SO₃H modification on the catalytic performance of PDS-1.0-F in the carbonylation of formaldehyde to glycolic acid was then investigated. The results show that after the CF₃SO₃H modification, the framework of PDS-1.0-F catalyst was grafted with strong electron withdrawing groups. In comparison with PDS-1.0, the CF₃SO₃H-modified PDS-1.0-F catalyst has a lower surface area, pore volume and concentration of acid sites, but much stronger acidity and higher thermal stability. As a result, the PDS-1.0-F catalyst exhibits excellent performance in the carbonylation of formaldehyde and over it the yield of glycolic acid reaches 91.2%.
- formaldehyde carbonylation,
- glycolic acid,
- fluorosulfonic acid modification,
- sulfonic polymer,
- acid strength
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Study on the performance of CF₃SO₃H modified sulfonic polymer-based catalyst in formaldehyde carbonylation reaction