Citation: Yao Yu WANG, Qian SHI, Qi Zhen SHI, Yi Ci GAO, Zhong Yuan ZHOU. Synthesis and Crystul Structure of A New Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Triphenylphosphine and Methanol[J]. Chinese Chemical Letters, ;1998, 9(11): 1069-1072. shu

Synthesis and Crystul Structure of A New Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Triphenylphosphine and Methanol

1.
Department of Chemistry, Northwest University Xian 710069;
2.
Department of Chemistry, Lanzhou University, Lanzhou 730000;
3.
Chengdu Institute of Organic Chemistry, Chendou 610041

Received Date: 6 April 1998

Fund Project: This work was supported by National Natural Science Foundation of China.

Copper (Ⅱ) α-methacrylate reacts with triphenylphosphine to form mixed-valence copper (Ⅰ,Ⅱ) complex Cu₄ (CH₂=C(CH₃)COO)₆ (PPh₃)₄ (CH₃OH)₂ in methanol solution. The crystal and molecular structure of the complex has been determined by single crystal X-ray structural analysis. This material forms pale green crystals with triclinic symmetry, space group Pi, a=1.3567(2) nm, b=1.3946(3)nm, c=1.4569(3)nm, α=66.069(14)°,β=84.234(14)°, γ=69.975 (13)°, R=0.0536.
- mixed-valence complex,
- synthesis,
- crystal structure
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