Citation: CAO Weixiao, ZHANG Peng, FENG Xinde. PHOTOINDUCED CHARGE TRANSFER POLYMERIZATION OF STYRENE INITIATED BY ELECTRON ACCEPTOR[J]. Chinese Journal of Polymer Science, ;1995, 13(3): 259-263. shu

PHOTOINDUCED CHARGE TRANSFER POLYMERIZATION OF STYRENE INITIATED BY ELECTRON ACCEPTOR

Received Date: 16 March 1994

Photoinduced charge transfer polymerization of styrene (St) with electron acceptor asinitiator was investigated. In case of fumaronitrile (FN) or maleic anhydride (MA) asinitiator the polymerization takes place regularly, whereas the tetrachloro-1, 4-benzenequinone (TCQ), 2, 3-dichloro-5, 6-dicyano-1, 4-benzenequinone (DDQ). ortetracyano ethylene (TCNE) as initiator the polymerization proceeds reluctantly only afterthe photoaddition reaction. A mechanism was proposed that free radicals would be formed following the charge and proton transfer in the exciplex formed between St and electron acceptors.
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