Citation: Guo Qiang SHANGGUAN, Arthur E. MARTELL, Zhong Ren ZHANG. The Synthesis of a New Macrocyclic Dinucleating Ligand,3,6,9,17,20, 23-Hexaaza-29,30-Dihydroxy-13,27-Dimethyl-Tricyclo[23,3,1,1^11,15]Triaconta-1(28),11,13, 15(30),25,26-Hexaene[J]. Chinese Chemical Letters, ;2000, 11(7): 573-576. shu

The Synthesis of a New Macrocyclic Dinucleating Ligand,3,6,9,17,20, 23-Hexaaza-29,30-Dihydroxy-13,27-Dimethyl-Tricyclo[23,3,1,1^11,15]Triaconta-1(28),11,13, 15(30),25,26-Hexaene

a Department of Chemistry, Jining Medical College, Jining 272013;
b Department of Chemistry, Texas A & M University, College Station, Texas 77842 USA

Received Date: 23 December 1999
Revised Date: 24 April 2000

Fund Project: The financial supported from the Robert A. Welch Foundation(A-0259) in the U.S Scholarship Council is gratefully acknowledged.

A new dinucleating 24-membered hexaazadiphenol macrocyclic ligand, 3,6,9,17,20, 23-hexaaza-29,30-dihydroxy-13,27-dimethyl-tricyclo[23, 3, 1, 1^{11, 15}] triaconta-1(28), 11,13, 15(30),25, 26-hexaene, BDBPH, was synthesized by the NaBH₄ reduction of the Schiff-base obtained from the[2+2] condensation between diethylenetriamine and diformyl-p-cresol. The structure was characterized by elemental analysis, ¹HNMR and FAB-MS. The synthetic method was also discussed.
- Macrocyclic ligand,
- synthesis
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