Citation: Zhong Sheng JIN, Ge Cheng WEI, Yung Shing LIU, Gang DONG, Chun Ting SUN, Qi Jun HUANG, Fan YANG. MOLECULAR AND CRYSTAL STRUCTURES OF TETRANUCLEAR MOLYBDENUM CLUSTER[MO₄(μ3-O)₂O₄Cl2(o-CH₃C₆H₄COO)⁶][J]. Chinese Chemical Letters, ;1990, 1(3): 245-246. shu

MOLECULAR AND CRYSTAL STRUCTURES OF TETRANUCLEAR MOLYBDENUM CLUSTER[MO₄(μ3-O)₂O₄Cl2(o-CH₃C₆H₄COO)⁶]

a Changchun Institute of Applied Chemistry Chinese Academy of Science Changchun 130022 China;
b Department of Chemistry Jilin University Changchun 130023 China

Received Date: 19 March 1990

The new cluster[MO₄(μ3-O)₂O₄Cl2(o-CH₃C₆H₄COO)⁶]has been prepared by the reaction of molybdenum pentachloride and o-methylbenzoic acid.The crystal and molecular structures were determined by the X-ray diffraction method.It crystallizes in the orthorhombic space group Pnna with cell parameters:Mr=1361.6, a=13.792(4), b=17.957(3), c=20.974(9)Å , V=5194(2) 3, Z=4, Dc=1.74/cm³, F(OOO)=2704, μ(MoKα)=11.0/cm, R=0.074.
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