Citation: Da Qing SHI, Lai Long MU, Zai Sheng LU, Gui Yuan DAI. Low-valent Titanium Induced Reductive Coupling Reaction of Aryl Sulfonyl Chlorides with α,β-Unsaturated Esters[J]. Chinese Chemical Letters, ;1997, 8(8): 677-678. shu

Low-valent Titanium Induced Reductive Coupling Reaction of Aryl Sulfonyl Chlorides with α,β-Unsaturated Esters

Department of chemistry, Xuzhou Normal University, Xuzhou, 221009

Received Date: 24 February 1997

Fund Project: This work was supported by the Science and Technology Youth Fund of Jiangsu Province.

The reductive coupling reactions of aryl sulfonyl chloride induced by (TiCl₄-Zn) reagent affords diaryl disulfide.However,reaction of aryl sulfonyl chloride with α,β-unsaturated ester under the same condition affords β-arylsulfo ester.
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