Citation: XIAO Guo-peng, QIAO Wei-jun, WANG Li-bao, ZHANG Lei, ZHANG Jian, WANG Hong-hao. Effect of calcination temperature of LaNiO₃ on CuO/LaNiO₃ catalyst for hydrogen production via methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(2): 213-220. shu

Effect of calcination temperature of LaNiO₃ on CuO/LaNiO₃ catalyst for hydrogen production via methanol steam reforming

College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushan 113001, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com
Received Date: 28 October 2019
Revised Date: 29 December 2019

Fund Project: the National Natural Science Foundation of China 21376237Natural Science Fund in Liaoning Province 2019-MS-221Scientific research funds project of Liaoning education department L2019038The project was supported by the National Natural Science Foundation of China (21376237), Scientific research funds project of Liaoning education department (L2019038) and Natural Science Fund in Liaoning Province (2019-MS-221)

Figures(10)

The LaNiO₃ perovskite support was synthesized by sol-gel method. The CuO/LaNiO₃ catalyst was prepared by impregnation method. The catalyst was characterized by XRF, XRD, BET, H₂-TPR and XPS. The effect of calcination temperature of LaNiO₃ perovskite on the structure of CuO/LaNiO₃ catalyst and its catalytic performance for methanol steam reforming were investigated. The results show that the calcination temperature of the support mainly affects the surface oxygen vacancy of the catalyst, the interaction between the active component and the support. When the calcination temperature of the support is 800℃, the surface of the catalyst has more oxygen vacancy, and the interaction between the active component and the support is stronger. Therefore, the hydrogenation activity of methanol steam reforming is higher.
- perovskite,
- methanol steam reforming,
- hydrogen,
- calcination temperature
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Effect of calcination temperature of LaNiO3 on CuO/LaNiO3 catalyst for hydrogen production via methanol steam reforming

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Effect of calcination temperature of LaNiO₃ on CuO/LaNiO₃ catalyst for hydrogen production via methanol steam reforming