Citation: Hua Chang JIANG, Wei Min LU, Hui Lin WAN. Effect of Different Dopant in the Mo-V-Te-O Catalyst on the Performance of Selective Oxidation Propane to Acrolein[J]. Chinese Chemical Letters, ;2004, 15(8): 977-980. shu

Effect of Different Dopant in the Mo-V-Te-O Catalyst on the Performance of Selective Oxidation Propane to Acrolein

1.
Institute of Catalysis, Zhejiang University(Xixi Campus), Hangzhou 310028;
2.
Department of Chemistry, Xiamen University, Xiamen 361005

Received Date: 9 July 2003

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 20173049) and The State Key Laboratory for Physical Chemistry of Solid Surface of Xiamen University.

Several Mo-V-Te-O mixed metal oxides catalysts with different dopant were prepared and used for catalytic oxidation propane to acrolein.It was revealed that the addition of P could greatly improve the performance of the Mo-V-Te-O catalyst.The catalysts were examined by XRD and H₂-TPR.The XRD characteristic of the Mo-V-Te-P-O showed that the addition of P could aggrandize the (V_0.07Mo_0.93)₅O₁₄ phase.H₂-TPR illuminated that the MoV_0.3Te_0.23P_0.15O_n catalyst took on the best redox ability.
- Acrolein,
- mixed metal oxides catalysts,
- selective oxidation,
- propane,
- XRD
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