Citation: Li Dan, Zhu Suhui, Feng Yimin, Liu Lili, Zhang Hongyan, Zhang Yunchen. Preparations and Catalytic Properties of Gemini Surfactant (16-n-16) Stabilized Gold Nanoparticles[J]. Chemistry, ;2018, 81(4): 366-371. shu

Preparations and Catalytic Properties of Gemini Surfactant (16-n-16) Stabilized Gold Nanoparticles

College of Chemistry & Chemical and Environmental Engineering, Weifang University, Weifang 261061

Received Date: 29 December 2017
Accepted Date: 27 January 2018

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Gemini surfactants can be used as surface stabilizers for preparing gold nanoparticles (AuNPs) due to their special structures. The particle size and stability of AuNPs were affected by different spacers in the structure of gemini surfactants significantly. Gold nanoparticle colloids were prepared with the gemini surfactants (16-n-16, n=2, 3, 4 and 6). The effect of pH value on the stability of AuNPs in the dispersion systems was investigated. The catalytic property of the AuNPs on hydrogenation of 4-nitrophenol was studied. 16-4-16 and 16-3-16 have good effect on stabilizing AuNPs. 16-3-16-AuNPs showed the best stability in different pH environment. The catalytic activity of 16-4-16-AuNPs in 4-nitrophenol hydrogen reduction reaction was better than others.
- Gemini surfactant,
- Colloid,
- Gold nanoparticles,
- Catalytic degradation
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沈阳化工大学材料科学与工程学院沈阳 110142