Citation: Jian Quan LU, Li ZHANG, Ting Quan SUN, Gui Xiang WANG, Ling Yan WU. Synthesis of Coumarin-functionalized Calix[4]arene and Selective Recognition for L-Tryptophan[J]. Chinese Chemical Letters, ;2006, 17(5): 575-577. shu

Synthesis of Coumarin-functionalized Calix[4]arene and Selective Recognition for L-Tryptophan

Hubei Key Laboratory of Bioanalytical Technique, Hubei Normal University, Huangshi 435002

Received Date: 26 September 2005

Fund Project: This work was financial supported by the Science Foundation of the Education Department of Hubei Province (Project Z200522002) and the Open Foundation of Hubei Key Laboratory of Biotechnology in Traditional Chinese Medicine (Project 20040201).

5, 11, 17, 23-Tetra-tert-butyl-25, 27-bis(7'-methoxycoumarin-3'-methyloxy)-26, 28-dihydroxycalix[4]arene was synthesized and characterized. The derivative could recognize L-tryptophan with a 1:1 complexing ratio and an apparent equilibrium constant of 111 L mol^-1 in DMF-acetonitrile as solvent by UV-visible and fluorescent spectrophotometry.
- Calixarene,
- synthesis,
- recognition,
- L-tryptophan
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