Citation: Wang Tingting, Song Yu, Zhang Minna, Zhang Heng. Preparation of Cesium Tungsten Bronze and Its Catalytic Property for Glycerol Dehydration to Acrolein[J]. Chemistry, ;2019, 82(11): 1008-1012. shu

Preparation of Cesium Tungsten Bronze and Its Catalytic Property for Glycerol Dehydration to Acrolein

School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165

Received Date: 18 May 2019
Accepted Date: 16 August 2019

Figures(6)

Cesium tungsten bronze was synthesized by a hydrothermal method with ammonium paratungstate and cesium nitrate as raw materials. Ethylenediamine tetraacetic acid (EDTA) was used as both template and reductant in this system. The effects of preparation conditions, such as amount of EDTA, concentration of the precursor, ratio of Cs to W, on the composition and morphology of the products were investigated. The as-synthesized products was applied as catalyst to the dehydration of glycerol to acrolein, and the content of Cs in the cesium tungsten bronze was found to have significant effect on the catalytic property. The product with Cs/W molar ratio of 0.2:1 showed better performance than the others, with a glycerol conversion of 81.3% and a high selectivity of 92.9% to acrolein.
- Tungsten bronze,
- Hydrothermal,
- Glycerol,
- Acrolein
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沈阳化工大学材料科学与工程学院沈阳 110142