Citation: Hong Wei HOU, Xin Quan XIN, Xiao Xing HUANG, Jin Hua CAI, Bei Sheng KANG. SYNTHESIS AND STRUCTURE OF A NOVEL “BUTTERFLY”CLUSTER“MoOS₃Cu₂(Py)₂(PPh₃)₂”[J]. Chinese Chemical Letters, ;1995, 6(1): 91-92. shu

SYNTHESIS AND STRUCTURE OF A NOVEL “BUTTERFLY”CLUSTER“MoOS₃Cu₂(Py)₂(PPh₃)₂”

a State Key Laboratory of Coordination Chemistry, Department of Chemistry, Nanking University, Nanjing 210093;
b Slate Key Laboratory of Struclural Chemistry, Fujian Institute of Research

Received Date: 29 August 1994

Reactions of [NH₄]₂MoO₂S₂,CuI and PPh₃ in Py produced mixed-metal cluster [MoOS₃Cu₂(Py)₂(PPh₃)₂],which crystallizes in the monoclinic,space group P2₁/a with a=18.149(4),b=10.044(3),c=25.171(7)Å,β=107.45(2) °,V=4377(2)Å³,Z=4,D_x=1.54,R=0.040,R_w=0.049.The results of structure determination show that the central unit of the cluster compound is composed of three metal and three sulfur atoms.
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